What is the BEST Liquid to Use for Most Potent Medicinal Value in Your Homemade Herbal Extracts?

NOTE: In this article, I’m sharing the five most common menstruums (also known as solvents) to use as the foundation to make herbal extracts and why you’d want to use one over another one. If you’ve ever wondered if you can use vinegar instead of alcohol for a certain purpose, this article will help answer your questions! Here are the five most common and generally best liquids most herbalists use to extract plant medicine.

As a new herbalist many years ago, I used to wonder which solvent (menstruum or base liquid) was the best for getting the most medicinal properties from the herbs I was using. Early on, I realized not all solvents are the same and they extract different herbal constituents, so I did some research to find out which ones are the best for our family’s needs.

For example, what is the best liquid to use to extract the nutritious minerals from nettle or dandelion leaf? Or, which liquid is best to use for root herbs? Why would I want to use a glycerine base instead of an herbal tea? I had heard that milk thistle shouldn’t be extracted in water….was this true? And if not, which liquid should I use to tincture my medicinal herbs the best way?

As I have started teaching others how to use herbs in their home and daily life in the past few years, I’ve noticed this question comes up a lot as beginning herbalists begin to experiment for themselves. You can find a lot of information on how to start using herbs in my free 5-Day Herbal Foundations email course and also in my Confident Herbalist Tribe membership community with over 50 masterclasses for students!

Once people realize you can’t just interchange a solvent like alcohol for vinegar for example, and get the same result in the extract, questions inevitably come up as to which menstruum is the best and why?

The answer is: It all depends.

It depends on a number of factors: the composition of the herbs being used, what you are using the preparation for, and the needs of the individual(s) using the extract.

All the solvents used for making herbal extracts have pros and cons, benefits and downsides.

Let’s find out which one(s) are the best for you to use in your herbal extract making.

I’ve written before about the different kinds of herbal extracts and also about water as a good solvent for extracting certain constituents from herbs. But here I’ll break down the chemical constituents (in general) that the different menstruums will best extract from the plant matter.

NOTE: I use the term menstruum interchangeably with the word solvent. They are the same thing. A solvent (menstruum) is simply the liquid chosen to extract the chemicals, or constituents, from the herb.

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What is the BEST Solvent or Menstruum for Extracting Chemical Constituents from Medicinal Herbs?

Let’s have a quick little chemistry review in order to understand how herbal extracts work. There are three chemistry words to know when creating your tinctures, and any kind of infusion, really: Solvent (menstruum), Solute, and Solution.

What is a Solvent, or Menstruum?

A menstruum is any liquid or viscous agent that is used to extract constituents from herbs through either heat, maceration, agitation, percolation, or a combination of other methods. Some common solvents include alcohol of varying proofs, vinegar (acetic acid), glycerine, water, honey, oils, and others.

These are essentially substances that break down a solid of some type, in this case plant matter, in order to extract the needed chemical constituents.

I’ll be discussing the five most commonly used menstruums in this article: alcohol, water, vinegar, glycerine, and oil. They’re not all equal, and they all have their strengths and weaknesses. It’s good to know these things as you decide how you want to get the best herbal preparation possible for your efforts.

What is the Solute?

The solutes are the plant materials that the solvent is responsible for breaking down to the extent needed to obtain the extract.

What is the Solution?

The solution, then, is the final product after complete maceration (breakdown) of the herbal matter. This would be your actual tincture, tea, infused oil, infused vinegar (acetum), etc.

You can see by using the actual chemistry of the process that there is nothing “woo-woo” about creating an herbal extraction or tincture or infused oil or whatever it is you choose to call it. It’s an actual scientific process of using a strong solvent to act upon a solute in order to obtain your desired solution.

Easy peasy!

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Now, let’s take a look at the different common solvents herbalists use to extract their herbal medicine from herbs:

1) Alcohol as a Menstruum:

Alcohol is the most common solvent for extracting herbal constituents. An alcohol extract is called a tincture, and these are easy to make and use for the home herbalist. Some herbal parts such as resins (the gooey sap from certain plants), require higher proofs of alcohol than others (see the list below), but most herbal parts extract just fine in 40% to 75% (80 proof to 150 proof) alcohol, such as vodka.

80 to 150 proof alcohol is considered a medium ethanol content extract, and is my favorite range of alcohol to use in our own personal tinctures. No dilution is required (generally), and it’s ready to go!

One of the reasons I like this range of alcohol proof is that the remaining percentage is water. You’ll see when I discuss water extracts coming up next why this range of alcohol proofs are great for obtaining the most desired chemical constituents possible (in most cases), in my opinion.

Essentially, when you use a mid-range “proof” of alcohol, you’re actually using a combination of alcohol and water. If you’re using a low proof, such as 60-80 proof, your solvent is 30-40% alcohol. If you’re using a high proof alcohol, for example 150-190 proof, your solvent is now 75 to 95 percent alcohol.

There are times you’d want to use a higher proof alcohol than a lower proof alcohol, however, a nice range to use if you’re new to herbalism, or even experienced, is 80 to 150 proof alcohol.

Here are the general elements alcohol extracts from the plant matter:

  • Essential oils

  • Alkaloids

  • Alkamindes

  • Glycosides

  • Acids

  • Acrids and bitters

  • Resins (needs the highest proof alcohol possible, up to 95%, which is 190 proof, such as Everclear)

Alcohol does NOT extract these elements well:

  • Minerals

  • Gums

  • Mucilage

So, if you are looking for a menstruum that will extract most of the medicinals from the plant matter, alcohol is a great choice. If you are wanting a more mineral rich extract for the nutritive value, then alcohol is not your best bet. Vinegar or water would be the better choices for the highest mineral extraction (see list below).

Another consideration is that alcohol is an excellent preservative. In my experience, an alcohol tincture made with 80 proof or higher alcohol (I have not tested lesser proof alcohol) will last for many years, even decades. I’ve used tinctures I’ve made over six years ago, and they are still potent and strong.

The downsides of using alcohol as an extract include:

  • Some people can’t or don’t want to take alcohol in any form

  • Concerns about using alcohol with children

But I should say here that the amount of alcohol you use in a typical dose is very small. You can find out more about dosing here.

Actually, most herbs do quite well in alcohol—-releasing their medicinal constituents for us. However, you need to consider the intention of what you’re making and what ingredients you want in your final solution, or extract.

Although alcohol extracts most constituents quite well, there are a few constituents that it just doesn’t extract well. Minerals, for example, don’t extract well in alcohol at all.

So, if you’re going to use a highly nutritious herb, such as dandelion leaf or nettle, and you want the advantages of the minerals in your formula, then alcohol wouldn’t be the best choice. In this case, water would be best!

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2) Water as a Menstruum:

Water, even though the preservative value is low, is my second favorite solvent for extracting necessary constituents from herbs. Water extracts include teas, decoctions, strong infusions, cold infusions, etc. Also, depending on the proof of the alcohol you choose to use, you will be getting some constituents in a tincture extracted with the water.

The problem with water extracts is that they only last for a couple of days, even refrigerated. This is because bacteria thrives in water.

However, the upside is that water is actually a fairly good solvent for extracting a range of constituents. According to Thomas Easley in his book The Modern Herbal Dispensatory, water extracts these constituents quite well:

  • Minerals (yes!)

  • Mucilage

  • Aromatic & simple bitters

  • Acrid compounds

  • Tannins (astringent herbs)

  • Starches and carbohydrates (tonic and sweet herbs)

Water does NOT extract these compounds well:

  • Essential or volatile oils

  • Resins

  • Oils

NOTE: You can probably now see why I personally enjoy alcohol proofs of 80 to 120 (and most often simple 80 proof). Because a good portion (40-50%) of the alcohol in this proof range is alcohol, and the remaining is considered to be water, you already have a nice combination without doing anything extra as far as measuring out solvents in specific ratios for the broadest extraction of constituents.

With this said, if your aim is to create a highly nutritious (instead of medicinal) extract, pure water is the best way to go. Alcohol tinctures of high mineral content herbs such as nettle, chickweed, horsetail, etc. are just not going to give the nutritive power that a good old strong water infusion will.

Personally, I love my herbal teas and strong infusions. They really can’t be made ahead, but when you make herbal teas, it gives you a chance to really enjoy the plant matter right before you drink it up!

Here is an article about different kinds of water extracts to consider making. They’re not all teas!

You can find out more about making herbal teas in my course with recipes: The Art of Creating Herbal Teas for Pleasure and Health.

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3) Glycerine as a Solvent:

Glycerine is my third favorite extractive to use. It’s actually a form of alcohol (glyceric alcohol) and is the by-product of the saponification process in soap making. This is one reason why handmade soaps are so wonderful: They retain the natural glycerine, whereas commercial soaps do not.

Glycerine is exceptional for soothing and softening the skin. You can find out more about natural soap making here: How to Create Your Own Handmade, Natural Hot Process Soaps.

For making herbal extracts, you’ll want to be sure to use food grade glycerine to ensure safety.

Glycerine extracts these compounds well:

  • Essential oils

  • Alkamindes from pungent herbs

  • Tannins (astringent herbs)

  • Acids (sour herbs)

  • Polysaccharides, saponins, and glycosides (from tonic, sweet herbs)

Glycerine does NOT extract these constituents well:

  • Aromatic bitters

  • Resins

  • Minerals

  • Mucilage (although it extracts better than alcohol)

In my personal use, I rarely use glycerites. They are too sweet for me, and I just prefer to use and make tinctures for most of my medicinals. However, glycerine is wonderful for helping with compliance in taking herbal preparations by mouth because the taste is generally a tad better than alcohol tinctures.

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4) Vinegar as an Herbal Solvent:

I love using vinegar to extract minerals and nutritives. Herbal vinegar extracts are wonderful for use externally as liniments, and internally as well. I think everyone is aware of the powers of raw apple cider vinegar as a health tonic, even without extracting beneficial herbal compounds.

Raw fruit vinegars are also useful in culinary endeavors, skincare, haircare, and more. When herbs are extracted in vinegar, you have a great health tonic!

For best potency, a vinegar should be at least 5% acetic acid, which is the element that extracts and preserves. If you are making your own homemade vinegars (see links above), you’ll want to be sure to test the pH if you want to use them for making extracts.

Extracts made using vinegar are called acetums.

Vinegar extracts these compounds well:

  • Minerals

  • Some essential oils

  • Some alkamindes (pungent herbs)

  • Some bitters (alkaloids)

You can see that vinegar as an extractive is not nearly as powerful as the above three menstruums.

Vinegar does not extract these compounds well:

  • Carbohydrates in tonic herbs (sweet herbs)

  • Mucilage

  • Oils

I actually make quite a lot of infused vinegars, mainly for cooking and using in skin and hair care. I also will use infused vinegars as cleaning agents around the house. Here’s a great all purpose cleaner to take a look at. Infuse some citrus peels along with the lavender, and you have a powerful, great smelling cleaning spray!

5) Oil as an Herbal Menstruum:

I love my herb infused oils! I always have several herbal oils infusing at a time. They are great for cooking, as well as fabulous in making body care products like salves and soaps. Infused oils are excellent additions to your home first aid kit too.

In general, though, oils are quite a poor solvent for most compounds.

Here are the constituents oil extracts well:

  • Essential oils

  • Aromatic & pungent herbs (alkamindes and some resins)

  • Flavonoids

  • Any oils in the herb

Pretty much, oils do not extract anything else very well, so you can see it’s pretty limited as a solvent.

Note: Much of this information was gleaned from Thomas Easley’s book, The Modern Herbal Dispensatory, and there is a full list of the resources I used at the end of this article for further reading as well.

Healthy Bones Herbal Blend

Healthy Bones Herbal Blend

Healthy Bones Tea Blend, An Example

I recently made an herbal blend for supporting the skeletal system and healthy bones. The nice thing about making herbal blends is you can often use them in different herbal preparations! I meant this blend specifically for tea, a water infusion.

The reason I decided to make this blend into a water infusion, or herbal tea, rather than a tincture is because the herbs it contains are very high in mineral and nutritive content, specifically to support bone, skin, hair, and nail health with its collagen and connective tissue supporting constituents.

You can see a video of me creating this blend on YouTube. I also discuss formulating teas.

Anyhow, if I wanted to, I could also use vinegar as a solvent for this blend because it works great for extracting minerals and nutritives. Then I would use that vinegar in cooking, as a drinking tonic, etc.

However, I would not use this blend for the reasons I created it (as a nutritional supplement and bone support) in an alcohol or glycerine extract because they just wouldn’t be effective for my needs.

These are different raw fruit vinegars I made last summer. All are 5% acetic acid or above and are just fine for creating an herbal extract (acetum).

These are different raw fruit vinegars I made last summer. All are 5% acetic acid or above and are just fine for creating an herbal extract (acetum).

Can You Combine Menstruums for the Best Extract?

The answer to this question is yes, you can. For example, many herbalists will add a bit of alcohol to their oil or vinegar infusions in order to extract a bit more of the constituents alcohol can handle. Also, being that alcohol is the best preservative out of all the solvents, some people like to add alcohol to their herbal syrups to increase the shelf life.

For alcohol to be used for preservative reasons, you’ll need at least 25% alcohol in the formula for best results.

As far as adding alcohol or water to these solvents, I think glycerine is the best menstruum to consider adding other solvents to. You can add some alcohol (although this defeats the purpose if you are using glycerine as an alternative to an alcohol tincture) or water to glycerine to obtain a nice extract.

In fact, I advocate adding 3/4 ratio of glycerine to 1/4 ratio of water to help the herbs release their constituents more easily into the extract. You can find out more about making extracts in my free 5-Day Herbal Foundations email course or my community herbalism membership, the Confident Herbalist Tribe.

There was an herbal store in Las Vegas, Nevada when I lived there that sold extracts with a combination of vinegar and glycerine. Very interesting. They were slightly sweet and quite tart. Frankly, I preferred the taste of my usual alcohol tinctures, but I could see where these would be handy for those who can’t take alcohol. Also, I suspect that in Las Vegas, alcohol tinctures probably require more specialized licensing.

Adding alcohol to vinegar can create a nice powerful broad spectrum extract too. This combination is called an acetous tincture. “Acetum or acetous” relates to vinegar.

You can also add a bit of alcohol to your oil infusions as well. It won’t really extend the life of the extract, as oil goes rancid depending on the type of oil it is and how old it is, and at that point, it’s no longer good. But the addition of alcohol may help extract extra constituents.

Avoid these common mistakes beginning herbalists make so you can make the best herbal medicine for YOU.

Herbal extracts are easy and fun to make! Find out how you can make your own safely and effectively!

Herbal extracts are easy and fun to make! Find out how you can make your own safely and effectively!

Final Thoughts on the Best Solvents (Menstruums) for Your Herbal Extracts

I know this was a kind of chemistry lesson article, but I think you’ll agree it’s pretty useful to know what works and what doesn’t in making your herbal extracts.

I’ve seen too many beginning herbalists (myself included way back in the early days of my medicine making) make the assumption that you can simply substitute one solvent for another, thinking you might only get a “weaker” extract (for example, alcohol versus vinegar).

The fact of the matter is, you won’t get the same kind of extract at all.

I’d love comments in the comments section if you think I’ve missed anything or you would like to add any other information!

Good luck in your herbal endeavors, and I hope you’ll join us in the free 5-Day Herbal Foundations email course so you can get started making your own home remedies and herbal medicines today!

You might also enjoy these related articles and/or videos:

What is a Tincture? How to Make and Use Herbal Tinctures

Make Your Own Effective Sleep Aid

The Measurement (Standardized) Method vs. The Folk Method in Making Tinctures: Which is Best?

How to Make Your Own Natural Aspirin (YouTube video)

How to Make a Pain Relief Salve (YouTube)

How to Make a Pain Relief Salve (Website)

And there are SO many more on the website and on my YouTube channel! So head on over, browse around, and enjoy! :-)

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If you’re not ready for a full-on herbalism course, but are interested in learning more, consider my FREE 5-Day Herbal Foundations email course, and start making home remedies today!

Hugs, Health, and Self-Reliance,

Heidi

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Elder flower tincture——

Elder flower tincture——

References:

Cech, Richo. Making Plant Medicine. Horizon Herbs. 2000.

Easley, T. and Horne, S. The Modern Herbal Dispensatory: A Medicine Making Guide. North Atlantic Books. 2016.

Green, James. The Herbal Medicine Maker’s Handbook. Crossing Press. 2000.

Nagel, Glen. Traditional Roots Conference 2017. Mastering Menstruums in Herbal Extracts: https://traditionalroots.org/files/2017/04/Mastering-Menstruums-in-Herbal-Extracts-final-5_16.pdf

http://blog.indieherbalist.com/which-is-better-glycerin-vs-alcohol-for-the-best-extracts/

https://organicgrowersschool.org/wp-content/uploads/2013/06/Herbal-Extractions-and-Preparations.pdf

If you are an herbalist or make any of your own herbal extracts at home, you’ve probably wondered which is the best solvent, or liquid base, to use? Alcohol, vinegar, glycerine, water, and oil? Which to choose? Here is a guide to help you decide whi…

If you are an herbalist or make any of your own herbal extracts at home, you’ve probably wondered which is the best solvent, or liquid base, to use? Alcohol, vinegar, glycerine, water, and oil? Which to choose? Here is a guide to help you decide which menstruum is the best to use when making your home remedies. #homeremedy #naturalremedy #menstruum #solvent #herbalism #herbalextract #extract #healingharvesthomestead

Disclaimer: I am not a medical doctor. In no manner, stated or implied is any of my content meant to treat, cure, diagnose, or prevent any illness or disease. Please be sure to seek medical advice from your medical professional before using herbs or essential oils. These statements have not been evaluated by the FDA.